Mistakes
to Avoid in Design & Operation of Reverse Osmosis Systems
By: Gil K. Dhawan Ph.D., P.E.,
Applied Membranes, Inc.
Introduction
Reverse Osmosis technology is evolved into a widely used
process for the purification of water. Well designed and properly
operated systems give a trouble-free performance over long periods of
time. Membranes in these systems have a long useful life. On
the other hand mistakes made during the design or operation of reverse
osmosis systems can lead to ongoing problems and reduced membrane life.
This article reviews some of the common mistakes made
during the design and operation of the reverse osmosis systems.
Membrane Performance
There is one simple but extremely important fact in
keeping the membranes at their peak performance:
"Keep the membrane surface Clean".
All impurities in water are removed at the membrane
surface. The dynamics of this separation step must ensure that
concentrated materials are not accumulating at the membrane surface.
If concentrations are allowed to build up near the membrane, precipitation
of low solubility substances will follow resulting in a decline in
membrane performance.
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Water
Analysis
Understanding the water analysis and the potential
problems caused by the sparingly soluble substances are crucial for the
success of a reverse osmosis system. Many reverse osmosis systems
have been designed and sold with no or incomplete water analysis.
Some of these mistakes are difficult to fix in teh field and may even
require discarding the existing system and starting all over again.
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Recovery
Recovery is defined as the ration of the permeate flow to
feed flow.
% Recovery = (Permeate Flow ÷ Feed Flow) x 100
In residential systems the recovery is expressed in terms
of ratio of brine flow to permeate flow. For example, the brine:
permeate flow ration may be 5:1. This can be converted into recovery
as follows:
Feed flow = Permeate Flow + Brine Flow
% Recovery = (Permeate Flow x 100) ÷ Feed Flow
or = 100 ÷ 6 = 16.7%
It is recommended that for most tap waters the recovery
for each membrane be maintained between 10 to 15%. Operating
membranes at higher than recommended recovery will result in fouling of
the membrane surface.
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Membrane Flux
All membranes have one common limitation. They can
only produce a maximum flow of a certain maximum permeate flow for a given
water. This limit is controlled by the quality of feed water and not
by the make of the membrane. For example, a maximum permeate flow
for most tap water applications is 25 gallons per square foot per day.
When membranes are run at fluxes higher than this value, fouling takes
place.
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Feed Flow
A minimum feed flow must be maintained throughout the
membrane. Feed velocity helps to reduce build up of concentrated
materials at the membrane surface. When several membranes are being
used, the arrangement of these membranes is crucial in maintaining proper
flow velocities. This arrangement must be checked against other
related factors such as higher pumping costs, recycle flow, etc.
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System
Shut-Down
Fouling tendency of feed water when flowing through
membranes is quite different than that of stagnant water at shut down.
Certain suspended solids may settle on membrane surface during stagnant
periods. On the other hand silica is found to crystallize during
shut down. A proper flush cycle can eliminate these problems.
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Residential Systems
Residential reverse osmosis systems need to take into
consideration all of the parts described above. In addition, there
are some other factors that require special attention in residential
systems. Most of these concerns are due to an improper selection of
some key components in the manufacturing of these systems.
-
Flow Restrictors: Poor quality flow
restrictors may cause systems to run at higher recoveries resulting in
shorter membrane life.
-
Prefilters: Sediment and carbon filters
used in the pretreatment of the residential systems must not shed fibers
or release carbon fines.
-
Check Valves: A faulty check valve can
cause a back pressure on the permeate side of the membrane element
resulting in a physical damage to the membrane.
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Summary
Mistakes in the design and operation of reverse osmosis
systems can be avoided by following the recommendations outlined in this
paper. There are no short cuts in providing systems that give
trouble free performance with a long useful membrane life.
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Diagrams and
References
Concentration
Polarization
- Increase in Soute Diffusion
- Possible Saturation/Precipitation
- Decrease in Net Pressure
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% Recovery = (Permeate ÷
Feed) x 100
% Recovery |
Concentrate
Concentration |
50 |
x 2 Feed
Conc. |
75 |
x 4 Feed
Conc. |
90 |
x 10 Feed
Conc. |
Concentrate Conc. = (100 ÷
[100-R]) x Feed Conc.
R = % Recovery |
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Higher Feed
Flow Helps to Reduce Membrane Fouling
Example:
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